WebRob joined the Department of Chemistry at Princeton University in the summer of 2011, where his group’s work has focused primarily on the applications of proton-coupled …

Publications – The Knowles Group - Princeton University

Webcandidate at Princeton in Robert Knowles’ group and is engaged in developing new applications of PCET to organic synthesis. Robert Knowles was born and raised in the … WebBy using photoredox proton-coupled electron transfer (PCET)/Ni dual-catalysis, a highly regio- and diastereoselective amidoacylation of unactivated olefins has been developed. Various acyl electrophiles are compatible, including alkyl- and aryl acyl chlorides and anhydrides, as well as in situ activated carboxylic acids. city of buhl water

Robert R. Knowles - Publications

http://renaud.dcb.unibe.ch/topic-review/topic-review-2016/tr2016_05_robert_knowles_pc.pdf WebApr 1, 2024 · Herein, we report the enantioselective addition of remote alkyl radicals, generated from the ring opening of unstrained cycloalkanols by a proton-coupled electron transfer (PCET) process, to 2-acyl imidazoles previously coordinated to a rhodium-based chiral Lewis acid. High yields and enantioselectivites up to 99% are achieved in 1 h. WebSep 3, 2016 · Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O-H Bonds. ... The Knowles Group • Prof. Robert Knowles • Department of Chemistry, Princeton University ... Room 188 • Princeton, NJ 08544 Email Rob • Phone: 609-258-7020. Powered by WordPress Theme: Talon by aThemes. #2 (no title) A New Me! Events; … city of brenham utility payment